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      "structure": {
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        "molfile": "L-Leucine, L-tyrosyl-D-alanylglycyl-L-phenylalanyl-\n  Marvin  01132104302D          \n\n 41 42  0  0  1  0            999 V2000\n   18.8357   -3.6577    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0\n   19.5502   -4.0702    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   19.5502   -4.8952    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   20.2647   -5.3077    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   20.2647   -6.1327    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   19.5502   -6.5453    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   18.8357   -6.1327    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   18.8357   -5.3077    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   18.8357   -2.8327    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   19.5502   -2.4202    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0\n   20.2647   -2.8327    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0\n   20.2647   -3.6577    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   20.9792   -4.0702    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   20.9792   -4.8952    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   21.6937   -3.6577    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   20.9792   -2.4202    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   21.6937   -2.8327    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n   20.9792   -1.5952    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n   18.1213   -2.4202    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n   18.1213   -4.0702    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0\n   17.4068   -3.6577    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   16.6923   -4.0702    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   15.9779   -3.6577    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0\n   15.2633   -4.0702    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   14.5488   -3.6577    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0\n   13.8344   -4.0702    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0\n   13.1199   -3.6577    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   12.4054   -4.0702    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0\n   11.6909   -3.6577    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   10.9765   -4.0702    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   10.9765   -4.8952    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   10.2620   -5.3078    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    9.5475   -4.8952    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    9.5475   -4.0702    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   10.2620   -3.6577    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    8.8330   -5.3078    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n   12.4054   -4.8952    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0\n   13.1199   -2.8327    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n   14.5488   -2.8327    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   15.2633   -4.8952    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n   17.4068   -2.8327    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n  1  2  1  0  0  0  0\n  2  3  1  0  0  0  0\n  3  4  2  0  0  0  0\n  4  5  1  0  0  0  0\n  5  6  2  0  0  0  0\n  7  6  1  0  0  0  0\n  8  7  2  0  0  0  0\n  3  8  1  0  0  0  0\n  1  9  1  6  0  0  0\n  9 10  1  0  0  0  0\n 10 11  1  0  0  0  0\n 11 12  1  0  0  0  0\n 12 13  1  0  0  0  0\n 13 14  1  0  0  0  0\n 13 15  1  0  0  0  0\n 11 16  1  6  0  0  0\n 16 17  1  0  0  0  0\n 16 18  2  0  0  0  0\n  9 19  2  0  0  0  0\n  1 20  1  0  0  0  0\n 20 21  1  0  0  0  0\n 21 22  1  0  0  0  0\n 22 23  1  0  0  0  0\n 23 24  1  0  0  0  0\n 24 25  1  0  0  0  0\n 25 26  1  0  0  0  0\n 26 27  1  0  0  0  0\n 27 28  1  0  0  0  0\n 28 29  1  0  0  0  0\n 29 30  1  0  0  0  0\n 30 31  2  0  0  0  0\n 31 32  1  0  0  0  0\n 32 33  2  0  0  0  0\n 34 33  1  0  0  0  0\n 35 34  2  0  0  0  0\n 30 35  1  0  0  0  0\n 33 36  1  0  0  0  0\n 28 37  1  1  0  0  0\n 27 38  2  0  0  0  0\n 25 39  1  6  0  0  0\n 24 40  2  0  0  0  0\n 21 41  2  0  0  0  0\nM  END",
        "smiles": "CC(C)C[C@@H](C(=O)O)NC(=O)[C@H](Cc1ccccc1)NC(=O)CNC(=O)[C@@H](C)NC(=O)[C@H](Cc2ccc(cc2)O)N",
        "formula": "C29H39N5O7",
        "atropisomerism": "No",
        "charge": 0,
        "count": 1,
        "stereochemistry": "ABSOLUTE",
        "defined_stereo": 4,
        "ez_centers": 0,
        "molecular_weight": "569.6504",
        "optical_activity": "UNSPECIFIED",
        "references": [
          "e076b512-9528-d429-91fe-0b4475805e72",
          "3a966455-d0fc-48eb-ba19-889ff942c54f"
        ],
        "stereo_centers": 4
      },
      "unii": "PO4D55T1IG"
    }
  ]
}