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            "refuuid": "bff08fb4-6520-4699-b32a-083bca27e6b5",
            "name": "6-EPIMEDROXYPROGESTERONE ACETATE",
            "unii": "275N4RXX0Q",
            "linking_id": "275N4RXX0Q",
            "ref_pname": "6-EPIMEDROXYPROGESTERONE ACETATE",
            "substance_class": "reference"
          }
        },
        {
          "uuid": "bc131206-e52e-435a-b64a-51b27b91c6a9",
          "amount": {
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            "type": "RELATIONSHIP_AMOUNT",
            "units": "PERCENT PEAK AREA",
            "high_limit": 0.1
          },
          "qualification": "EP",
          "type": "IMPURITY->PARENT",
          "interaction_type": "CHROMATOGRAPHIC PURITY (HPLC/UV)",
          "references": [
            "db232321-18d1-484f-810b-5839906f859f"
          ],
          "related_substance": {
            "uuid": "a770cc73-7e0f-406a-9900-12955cae94fc",
            "refuuid": "bff08fb4-6520-4699-b32a-083bca27e6b5",
            "name": "6-EPIMEDROXYPROGESTERONE ACETATE",
            "unii": "275N4RXX0Q",
            "linking_id": "275N4RXX0Q",
            "ref_pname": "6-EPIMEDROXYPROGESTERONE ACETATE",
            "substance_class": "reference"
          }
        },
        {
          "uuid": "a4958db2-e350-410a-a6f7-df1577b075f4",
          "amount": {
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            "type": "RELATIONSHIP_AMOUNT",
            "units": "PERCENT PEAK AREA (CORRECTION FACTOR)",
            "high_limit": 0.5
          },
          "comments": "For the calculation of contents, multiply the peak areas by 1.8",
          "qualification": "EP",
          "type": "IMPURITY->PARENT",
          "interaction_type": "CHROMATOGRAPHIC PURITY (HPLC/UV)",
          "references": [
            "db232321-18d1-484f-810b-5839906f859f"
          ],
          "related_substance": {
            "uuid": "f2078a73-56a4-409e-832d-85ade03c366c",
            "refuuid": "4cf6f33a-7c06-415d-a460-6d2f553e3d3e",
            "name": "4,5-DIHYDROMEDROXYPROGESTERONE ACETATE",
            "unii": "30R4R25OEY",
            "linking_id": "30R4R25OEY",
            "ref_pname": "4,5-DIHYDROMEDROXYPROGESTERONE ACETATE",
            "substance_class": "reference"
          }
        },
        {
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          "amount": {
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            "type": "RELATIONSHIP_AMOUNT",
            "units": "PERCENT PEAK AREA",
            "high_limit": 0.2
          },
          "comments": "MEDROXYPROGESTERONE ACETATE Impurity G.\nIn the chromatogram obtained with solution (1):the area of any peak corresponding to impurity G, when multiplied by a correction factor of 2.6, is not greater than 2 times of the area of the principal peak obtained with solution (3) (0.2%).",
          "type": "IMPURITY->PARENT",
          "references": [
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          ],
          "related_substance": {
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            "refuuid": "fcff748b-f729-4074-adaa-13e8809dccba",
            "name": "MEGESTROL ACETATE",
            "unii": "TJ2M0FR8ES",
            "linking_id": "TJ2M0FR8ES",
            "ref_pname": "MEGESTROL ACETATE",
            "substance_class": "reference"
          }
        },
        {
          "uuid": "798f275b-c05a-4863-b32c-f97748ce1f86",
          "amount": {
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            "type": "RELATIONSHIP_AMOUNT",
            "units": "PERCENT PEAK AREA (CORRECTION FACTOR)",
            "high_limit": 0.2
          },
          "comments": "For the calculation of contents, multiply the peak areas by 2.6",
          "qualification": "EP",
          "type": "IMPURITY->PARENT",
          "interaction_type": "CHROMATOGRAPHIC PURITY (HPLC/UV)",
          "references": [
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          ],
          "related_substance": {
            "uuid": "bda5a2a2-8b41-41a3-9927-6c37b9dab874",
            "refuuid": "fcff748b-f729-4074-adaa-13e8809dccba",
            "name": "MEGESTROL ACETATE",
            "unii": "TJ2M0FR8ES",
            "linking_id": "TJ2M0FR8ES",
            "ref_pname": "MEGESTROL ACETATE",
            "substance_class": "reference"
          }
        },
        {
          "uuid": "cf0ed200-ae8a-44ea-a84a-7acae20227e3",
          "amount": {
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            "type": "RELATIONSHIP_AMOUNT",
            "units": "PERCENT PEAK AREA",
            "high_limit": 0.2
          },
          "qualification": "EP",
          "type": "IMPURITY->PARENT",
          "interaction_type": "CHROMATOGRAPHIC PURITY (HPLC/UV)",
          "references": [
            "db232321-18d1-484f-810b-5839906f859f"
          ],
          "related_substance": {
            "uuid": "a3c37d9a-adb1-4425-866a-818e9bd7825d",
            "refuuid": "004fd299-4823-4d0b-9c43-b7eb02359d71",
            "name": "17A.BETA.-HYDROXY-6,17A-DIMETHYL-D-HOMOANDROST-4-ENE-3,17-DIONE",
            "unii": "M5G8OUR480",
            "linking_id": "M5G8OUR480",
            "ref_pname": "17A.BETA.-HYDROXY-6,17A-DIMETHYL-D-HOMOANDROST-4-ENE-3,17-DIONE",
            "substance_class": "reference"
          }
        },
        {
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          "amount": {
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            "type": "RELATIONSHIP_AMOUNT",
            "units": "PERCENT PEAK AREA",
            "high_limit": 0.65
          },
          "comments": "MEDROXYPROGESTERONE ACETATE Impurity H.\nThe following peaks are eluted at the following relative retention with reference to the peak of medroxyprogesterone acetate (retention time about 27 minutes): impurity H about 0.65.",
          "type": "IMPURITY->PARENT",
          "references": [
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            "refuuid": "a7525252-5743-418c-901e-ad967ab68fd9",
            "name": "HYDROXYPROGESTERONE ACETATE",
            "unii": "L124O66YSI",
            "linking_id": "L124O66YSI",
            "ref_pname": "HYDROXYPROGESTERONE ACETATE",
            "substance_class": "reference"
          }
        },
        {
          "uuid": "3759ab27-a1ee-4aef-b8d4-daae871d20dc",
          "comments": "UNSPECIFIED",
          "qualification": "EP",
          "type": "IMPURITY->PARENT",
          "references": [
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          ],
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            "refuuid": "a7525252-5743-418c-901e-ad967ab68fd9",
            "name": "HYDROXYPROGESTERONE ACETATE",
            "unii": "L124O66YSI",
            "linking_id": "L124O66YSI",
            "ref_pname": "HYDROXYPROGESTERONE ACETATE",
            "substance_class": "reference"
          }
        },
        {
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          "amount": {
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            "type": "RELATIONSHIP_AMOUNT",
            "units": "WEIGHT PERCENT",
            "high_limit": 103,
            "low_limit": 97
          },
          "qualification": "EP",
          "type": "BASIS OF STRENGTH->SUBSTANCE",
          "interaction_type": "ASSAY (UV)",
          "references": [
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          ],
          "related_substance": {
            "uuid": "19977af9-c7e2-48d9-a616-bbb2b6563d66",
            "refuuid": "339ba9df-cd88-49bb-9e7d-af168003ad56",
            "name": "MEDROXYPROGESTERONE ACETATE",
            "unii": "C2QI4IOI2G",
            "linking_id": "C2QI4IOI2G",
            "ref_pname": "MEDROXYPROGESTERONE ACETATE",
            "substance_class": "reference"
          }
        },
        {
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          "amount": {
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            "type": "RELATIONSHIP_AMOUNT",
            "units": "WEIGHT PERCENT",
            "high_limit": 103,
            "low_limit": 97
          },
          "qualification": "USP",
          "type": "BASIS OF STRENGTH->SUBSTANCE",
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          "references": [
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            "name": "MEDROXYPROGESTERONE ACETATE",
            "unii": "C2QI4IOI2G",
            "linking_id": "C2QI4IOI2G",
            "ref_pname": "MEDROXYPROGESTERONE ACETATE",
            "substance_class": "reference"
          }
        },
        {
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          "type": "ACTIVE MOIETY",
          "related_substance": {
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            "refuuid": "cf6010c0-27bc-4fa7-9468-1037061914dd",
            "name": "MEDROXYPROGESTERONE",
            "unii": "HSU1C9YRES",
            "linking_id": "HSU1C9YRES",
            "ref_pname": "MEDROXYPROGESTERONE",
            "substance_class": "reference"
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        },
        {
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          "comments": "The following peaks are eluted at the following relative retention with reference to the peak of medroxyprogesterone acetate (retention time about 27 minutes): impurity C about 0.8. The test is not valid unless in the chromatogram obtained with solution (4) the resolution factor between the peaks due to impurity G and due to medroxyprogesterone acetate is at least 3.3. In the chromatogram obtained with solution (1):the area of any peak corresponding to impurity C, E or I is not greater than 2 times the area of the principal peak obtained with solution (3) (0.2%).",
          "type": "IMPURITY->PARENT",
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            "unii": "WP7MO40OC6",
            "linking_id": "WP7MO40OC6",
            "ref_pname": "6.ALPHA.,17A.BETA.-DIMETHYL-3,17-DIOXO-D-HOMOPREGN-4-EN-17A.ALPHA.-YL ACETATE",
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          "comments": "MEDROXYPROGESTERONE ACETATE Impurity I.\nThe following peaks are eluted at the following relative retention with reference to the peak of medroxyprogesterone acetate (retention time about 27 minutes): impurity I about 0.5. In the chromatogram obtained with solution (1):the area of any peak corresponding to impurity C, E or I is not greater than 2 times the area of the principal peak obtained with solution (3) (0.2%).",
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            "ref_pname": "17aβ-Hydroxy-6α,17aα-dimethyl-D-homoandrost-4-ene-3-17-dione",
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          "preferred": false,
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          "preferred": false,
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          "smiles": "C[C@H]1C[C@@H]2[C@H](CC[C@@]3(C)[C@H]2CC[C@@]3(C(=O)C)OC(=O)C)[C@@]4(C)CCC(=O)C=C14",
          "formula": "C24H34O4",
          "atropisomerism": "No",
          "charge": 0,
          "count": 1,
          "stereochemistry": "ABSOLUTE",
          "count_amount": {
            "type": "MOL RATIO",
            "average": 1,
            "units": "MOL RATIO",
            "uuid": "ced177cf-d429-44f5-92a3-7710b59c678c"
          },
          "defined_stereo": 7,
          "ez_centers": 0,
          "molecular_weight": "386.5253",
          "optical_activity": "UNSPECIFIED",
          "stereo_centers": 7
        }
      ],
      "definition_level": "COMPLETE",
      "uuid": "339ba9df-cd88-49bb-9e7d-af168003ad56",
      "version": "42",
      "structure": {
        "id": "b09161d7-ae9f-4e2a-a716-2bf591465d05",
        "molfile": "\n  Marvin  01132109092D          \n\n 31 34  0  0  1  0            999 V2000\n    1.1336   -2.1015    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0\n    3.2610   -0.8774    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0\n    4.0737   -0.6185    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0\n    1.1336   -2.9323    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    2.5596   -2.1015    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0\n    1.8453   -1.7004    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0\n    3.2610   -1.7004    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0\n    2.5596   -2.9323    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    0.4037   -3.3542    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    1.8453   -3.3542    0.0000 C   0  0  2  0  0  0  0  0  0  0  0  0\n    2.5596   -0.4581    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    4.5473   -1.2940    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    4.9045   -0.2459    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n    1.8453   -0.8774    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    4.0737   -1.9463    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    0.4037   -1.7004    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    4.0737    0.2174    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    5.6835   -0.6677    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n   -0.3132   -2.9323    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    5.6835   -1.4416    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n    4.7052    0.6833    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n   -1.0327   -3.3542    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n   -0.3132   -2.1015    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    1.1336   -1.2940    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    3.2610   -0.0750    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    1.8453   -4.1850    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    6.2865   -0.2407    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    3.4370    0.7066    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    3.2610   -2.4354    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0\n    1.8402   -2.5157    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0\n    2.5545   -1.2811    0.0000 H   0  0  0  0  0  0  0  0  0  0  0  0\n  2 11  1  0  0  0  0\n  3  2  1  0  0  0  0\n  4  1  1  0  0  0  0\n  5  6  1  0  0  0  0\n  6  1  1  0  0  0  0\n  7  5  1  0  0  0  0\n  8  5  1  0  0  0  0\n  9  4  2  0  0  0  0\n 10  4  1  0  0  0  0\n 11 14  1  0  0  0  0\n 12 15  1  0  0  0  0\n  3 13  1  6  0  0  0\n 14  6  1  0  0  0  0\n 15  7  1  0  0  0  0\n 16  1  1  0  0  0  0\n  3 17  1  1  0  0  0\n 18 13  1  0  0  0  0\n 19 23  1  0  0  0  0\n 20 18  2  0  0  0  0\n 21 17  2  0  0  0  0\n 22 19  2  0  0  0  0\n 23 16  1  0  0  0  0\n  1 24  1  1  0  0  0\n  2 25  1  1  0  0  0\n 10 26  1  6  0  0  0\n 27 18  1  0  0  0  0\n 28 17  1  0  0  0  0\n  7 29  1  6  0  0  0\n  6 30  1  6  0  0  0\n  5 31  1  1  0  0  0\n 10  8  1  0  0  0  0\n 19  9  1  0  0  0  0\n  7  2  1  0  0  0  0\n 12  3  1  0  0  0  0\nM  END",
        "smiles": "C[C@H]1C[C@]2([H])[C@]([H])(CC[C@@]3(C)[C@@]2([H])CC[C@@]3(C(=O)C)OC(=O)C)[C@@]4(C)CCC(=O)C=C14",
        "formula": "C24H34O4",
        "atropisomerism": "No",
        "charge": 0,
        "count": 1,
        "stereochemistry": "ABSOLUTE",
        "defined_stereo": 7,
        "ez_centers": 0,
        "molecular_weight": "386.5253",
        "optical_activity": "UNSPECIFIED",
        "references": [
          "31155147-be84-4fbf-970f-3477e539cb0f",
          "20e98a8e-e086-4c79-914b-b3fe7e4eb7c4"
        ],
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      },
      "unii": "C2QI4IOI2G"
    }
  ]
}